不同基底上Au纳米粒子的2D组装与AFM表征
刘晓军, 宋丽云, 展宗城, 何 洪*,张桂臻,邱文革,訾学红
(北京工业大学环境与能源工程学院化学化工系催化化学与纳米科学研究室, 北京100124)
摘 要：从Au纳米粒子出发，利用竖直浸渍提拉法(dip-coating)成功将Au纳米粒子负载于基底(云母片/单晶硅片)，并以3-氨丙基三甲氧基硅烷(APTMS)对单晶硅片进行改性，得到具有密度分布不同的Au 纳米粒子two dimensional (2D)组装结构，制备方法简单易行。利用原子力显微镜(AFM)表征了不同制备条件下Au纳米粒子在基底表面的分布状态，结果表明，Au纳米粒子溶胶和偶联剂APTMS的浓度以及浸渍时间对Au纳米粒子在单晶硅片表面的密度分布起到决定性作用。
关键词：金纳米粒子;2D组装; 云母片; 单晶硅片;3-氨丙基三甲氧基硅烷
中图分类号：O614.123；O613.72；TG115.21+5.7 文献标识码：A
doi:10.3969/j.1000-6281.2014.02-006
2D assembly of Au nanoparticles on different substrates and AFM characterization
LIU Xiao-jun, SONG Li-yun, ZHAN Zong-cheng, HE Hong*, ZHANG Gui-zhen,
QIU Wen-ge, ZI Xue-hong
(Laboratory of Catalysis Chemistry and Nanoscience, Department of Chemistry and Chemical Engineering, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124，China)
Abstract：Through the dip-coating mode, Au nanoparticles were deposited on the mica and 3-aminopropyltrimethoxysilane modified silicon wafer, forming Au nanopartilces 2D-assembled structures with different density distributions. The distribution of Au nanoparticles on the substrates was characterized by atomic force microscopy (AFM) and the results showed that the concentrations of the Au nanoparticles sol and APTMS as well as the dipping time were the crucial factors to control the density distribution of Au nanoparticles on the silicon wafer.
Keywords：Aunanoparticles; two-dimensionalassembly; mica; silicon wafer；3-aminopropyltrimethoxysilane
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[1] Lewis L N.Chemical catalysis by colloids and clusters [J]. Chem Rev, 1993, 93(8), 2693 – 1730.
[2] El-Sayed M A.Some interesting properties of metals confined in time and nanometer space of different shapes [J]. Acc Chem Res, 2001, 34(4), 257 – 264.
[3] Peyser L A, Vinson A E, Dickson R M，et al. Photoactivated fluorescence from individual silver nanoclusters [J].Science, 2001, 291(5501), 103 – 106.
[4] Zhang X Y, Young M A, Van Duyne R P，et al. Rapid detection of an anthrax biomarker by surface-enhanced raman spectroscopy [J]. J Am Chem Soc, 2005, 127(12), 4484 – 4489.
[5] Taton T A, Mirkin C A, Letsinger R L. Scanometric DNA array detection with nanoparticle probes [J]. Science, 2000, 289(5485), 1757 – 1760.
[6] Chen J Y, Li X D, Xia Y N，et al.Gold nanocages: Bioconjugation and their potential use as optical imaging contrast agents [J]. Nano Lett, 2005, 5(3), 473 – 477.
[7] Beta C, Mikhailov A S, Ertl G，et al. Defect-mediated turbulence in a catalytic surface reaction [J]. Europhys Lett, 2006, 75(6), 868 – 874.
[8] Zhang Y W, Grass M E, Somorjai G B，et al.One-step polyol synthesis and Langmuir-Blodgett monolayer formation of size-tunable monodisperse rhodium nanocrystals with catalytically active (111) surface structures [J]. J Phys Chem C，2007, 111(33), 12243 – 12253.
[9] Cuenya B R.Synthesis and catalytic properties of metal nanoparticles: Size, shape, support, composition, and oxidation state effects [J].Thin Solid Films, 2010, 518(12), 3127 – 3150.
[10]Bharathi S, Joseph J, Lev O. Electrodeposition of thin gold films from an aminosilicate stabilized gold sol [J]. Electroche Solid-State Lett, 1999, 2(6), 284 – 287.
[11] Chandra R, Taneja P, Ayyub P，et al.Synthesis and TEM study of nanoparticles and nanocrystalline thin films of silver by high pressure sputtering [J]. Nano Stru Mater, 1999, 11(8)1171 – 1179.
[12]Fan C, Lu T, Li B F，et al. A new method for preparing nanometer-scale particles onto LB films [J]. Thin Solid Films, 1996, 286(1-2), 37 – 39.
[13]Giersig M, Mulvaney P P.Preparation of ordered colloid monolayers by electrophoretic deposition [J].Langmuir, 1993, 9(12), 3408 – 3413.
[14]Heath J R, Knobler C M, Leff D V.Pressure/temperature phase diagrams and superlattices of organically functionalized metal nanocrystal monolayers: the influence of particle size, size distribution, and surface passivant [J]. J Phys Chem B, 1997, 101(2), 189 – 197.
[15]Gorji M S, Razak K A, Cheong K Y. Gold nanoparticles deposited on linker-free silicon substrate and embedded in aluminum Schottky contact [J]. J Colloid Interface Sci, 2013, 408: 220 – 228.
[16] 江鹏，解思深，姚建年，等. 金纳米粒子有序膜结构的原子力显微研究[J].电子显微学报, 2001, 20 (5):5890 – 593.
[17] 姜德生，余海湖，周灵德. 自组装金纳米粒子薄膜AFM研究[J].电子显微学报, 2004, 23 (2):177 – 182.
[18] 屈钧娥，郭兴蓬，陈振宇，等.硫醇自组装多晶金表面AFM图像的分形研究[J].电子显微学报, 2010, 29 (2):129 – 135.
[19] Park Y, Yoo S H, Park S.Assembly of highly ordered nanoparticle monolayers at a water/hexane interface[J]. Langmuir, 2007, 23(21), 10505 – 10510.
[20]Hayakawa T, Usui Y, Bharathi S. Second harmonic generation from coupled surface-plasmon resonances in self-assembled gold-nanoparticle monolayers coated with an aminosilane [J].Adv Mater,2004, 16(16),1408–1412.
[21] Ji X H, Yang W, Peng X，et al. Size control of gold nanocrystals in citrate reduction: the third role of citrate [J]. J Am Chem Soc,2007, 129(45), 13939 – 13498.
[22]霍帅东，王东亮，梁兴杰，等. 聚乙二醇稳定的单分散超小金纳米颗粒的制备与表征[J]. 电子显微学报, 2013, 32(5):378 – 382.
[23] Chow M, Zukoski C. Gold sol formation mechanisms: role of colloidal stability [J]. J Colloid Interface Sci, 1994, 165(1), 97 – 109.
[24] NishimuraS,BiggsS, TateyamaT，et al. Molecular-scale structure of the cation modified muscovite mica basal plane [J]. Langmuir, 1994,10(12), 4554 – 4559.
[25] 方申文，段明，董兆雄，等. 云母表面改性的AFM研究[J]. 电子显微学报,2007,26 (3):199 – 203.
[26] 胡瑞省，刘善堂，刘忠范，等. 金纳米粒子在平整硅基表面上的组装[J]. 物理化学学报, 2000,16(3), 202 – 206.
[27] 王金清，杨生荣，王博，等. 单晶硅表面有机硅烷/Ag2O纳米微粒复合自组装膜的制备与表征[J].化学物理学报, 2003, 16(1), 41 – 44.
[28] 潘鹤，滕淑华，丁翠翠. 硅表面复合自组装膜的制备及其摩擦性能[J].物理化学学报, 2012, 28 (4), 917 – 922.
[29] 符小艺，牟涛，王健. 金纳米粒子在氨基表面上的组装-pH 值的影响[J].物理化学学报, 1998 , 14(11), 968 – 974.
[30] 方靖岳，秦石乔，张学骜，等. 氨基功能化有序介孔Si02薄膜组装Au纳米粒子复合材料的可调色散性质[J]. 高等学校化学学报, 2011, 32(7), 1460 – 1465.
[31]Bierbaum K, Kinzler M, Woll Ch，et al. A near edge X-ray absorption fine structure spectroscopy and X-ray photoelectron spectroscopy study of the film properties of self-assembled monolayers of organosilanes on oxidized Si( 100) [J].Langmuir, 1995,11(2), 512 – 518.
