准噶尔盆地东部芦草沟组介形类化石生油特征的扫描电镜研究
刘 金,王 剑,张晓刚,罗正江,尚 玲,王桂君
(中国石油新疆油田分公司实验检测研究院,新疆 克拉玛依 834000)
摘 要 为深化准噶尔盆地东部芦草沟组生烃母质认识,利用场发射扫描电镜与X射线能谱表征技术对介形类富有机质泥岩进行表征分析。结果表明,芦草沟组介形类生物化石分为钙质壳体和几丁质壳体两类。钙质壳体化石由白云石外壳、似蜂巢状几丁质中间层及内层层状几丁质三部分组成,几丁质壳体化石仅由几丁质组成。扫描电镜下芦草沟组有机质孔在20 nm~5 µm之间,发育于有机质碎屑之间,呈不规则状、狭缝状,有机质孔为几丁质碎屑缩聚形成的碎屑间孔隙及有机质碎屑边缘生烃形成的生烃孔隙的混合孔隙。介形类来源的有机质在低成熟-成熟热演化阶段形成有机质孔,并发生了大量生烃活动,介形类富有机质泥岩游离烃S1均值1.20 mg·g-1,壳体内部及壳体上见有大量生成的黑色重质组分油。研究结果打破了准噶尔盆地东部芦草沟组生烃母质主要为菌藻类的单一认识,对芦草沟组生烃母质的全面认识具有重要意义。研究同时对国内其它盆地介形类化石生烃研究具有启示意义。
关键词 介形类化石;生烃母质;扫描电镜;芦草沟组;准噶尔盆地
中图分类号:TE122.3;TE121.2;P575.2
文献标识码:Adoi:10.3969/j.issn.1000-6281.2021.06.007
Scanning electron microscope study on oil generation characteristics of ostracod fossils from the Lucaogou formation in eastern Junggar Basin
LIU Jin, WANG Jian, ZHANG Xiao-gang, LUO Zheng-jiang, SHANG Ling, WANG Gui-jun
(Research Institute of Experiment and Detection, Xinjiang Oilfield Company Petrochina, Karamay Xinjiang 834000, China)
Abstracts In order to deepen the understanding of the parent materials for hydrocarbon generation of the Lucaogou formation in the eastern Junggar basin, the ostracod fossils organic-rich mudstones were analyzed by field emission scanning electron microscopy(SEM) and X-ray energy spectrum(EDS). The results show that the ostracod fossils of the Lucaogou formation can be divided into calcareous shells and chitin shells. The calcareous shells consist of the dolomite shell, the mesosphere layer of the honeycombed chitin, while the inner layer of lamellar chitin. the chitin shells consist only of chitin. Under the scanning electron microscope, the organic pores of the Lucaogou formation were between 20 nm to 5 µm and developed among the organic clasts in an irregular and narrow slit shape. The organic pores were the mixed pores of Interclastic pores formed by the condensation of chitin clasts and the hydrocarbon-generating pores formed by hydrocarbon generation at the edge of organic clasts. The ostracods-derived organic matter formed organic pores during the low maturation to maturation thermal evolution stage with a lot of hydrocarbon generation occurred. Ostracods-rich mudstone had an average free hydrocarbon S1 of 1.20mg/g, and there were a lot of black heavy component oil in the shell and on the shell. The results break the single understanding that the parent material of the Lucaogou formation is mainly bacteria and algae in the eastern Junggar basin, and have important significance for a comprehensive understanding of the parent material of the Lucaogou formation. The study also shed light on the study of hydrocarbon generation characteristics of the ostracod fossils in other basins in China.
Keywords ostracod fossils;hydrocarbon generation material;scanning electron microscopy;the Lucaogou formation;Junggar basin
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[1] 马克,侯加根,刘钰铭,等. 吉木萨尔凹陷二叠系芦草沟组咸化湖混合沉积模式[J]. 石油学报,2017,38(6):636-648.
[2] 张亚奇,马世忠,高阳,等. 吉木萨尔凹陷芦草沟组致密油储层沉积相分析[J]. 沉积学报,2017,35(2):358-370.
[3] 张家武,何晶,陈硕,等. 第四纪湖相介形类壳体化石在古环境中的应用—种属组合研究进展与问题[J]. 地球科学进展,2009,24(11):1229-1237.
[4] 郑月娟,张健,张海华,等. 大兴安岭中段晚二叠世林西组介形虫化石及环境意义[J]. 吉林大学学报(地球科学版),2020,50(6):1776-1786.
[5] 董楠,朱立平,陈浩,等. 青藏高原赤布张错介形类反映的近13000年气候变化[J]. 第四纪研究,2021,41(2):434-445.
[6] 潘小明,姜开侠. 介形虫化石的电子探针分析及其有机质研究[J]. 石油实验地质,1989,11(2):195-202.
[7] 姚益民. 应用电镜研究介形虫壳体超微构造近况[C]. 中国古生物学会第十三,第十四届学术年会论文选集,1986:25-38.
[8] 熊志. 准噶尔盆地南缘中二叠统芦草沟组油页岩地球化学特征[D]. 长安:长安大学,2015.
[9] 新疆维吾尔自治区地质矿产局. 新疆维吾尔自治区区域地质志[M]. 北京:地质出版社,1993,136-169.
[10] 焦淑静,张慧,薛东川,等. 泥页岩有机显微组分的扫描电镜形貌特征及识别方法[J]. 电子显微学报,2018,37(2):137-144.
[11] 高凤琳,王成锡,宋岩,等. 氩离子抛光—场发射扫描电镜分析方法在识别有机显微组分中的应用[J]. 石油实验地质,2021,43(2):360-367.
[12] 高岗,向宝力,李涛涛,等. 吉木萨尔凹陷芦草沟组致密油系统的成藏特殊性[J]. 沉积学报,2017,35(4):824-833.
[13] 柯友亮,王华,甘华军,等. 准噶尔盆地南缘芦草沟组上段油页岩有机地球化学特征及其沉积意义[J]. 地质科技情报,2019,38(3):199-207.
[14] 彭雪峰,汪立今,姜丽萍. 准噶尔盆地东南缘芦草沟组油页岩元素地球化学特征及沉积环境指示意义[J]. 矿物岩石地球化学通报,2014,31(2):121-127.
[15] 朱国华,张杰,姚根顺,等. 沉火山尘凝灰岩:一种赋存油气资源的重要岩类—以新疆北部中二叠统芦草沟组为例[J]. 海相油气地质,2014,19(1):1-7.
[16] 徐建兵,张毅,张鑫,等. 页岩热成熟过程中残余干酪根演化特征[J]. 地球化学,2019,48(6):521-532.
[17] 朱如凯,白斌,崔景伟,等. 非常规油气致密储集层微观结构研究进展[J]. 古地理学报,2013,15(5):615-623.
[18] 丁江辉,张金川,杨超,等. 页岩有机孔成因演化及影响因素探讨[J]. 西南石油大学学报(自然科学版),2019,41(2):33-44.
[19] 焦淑静,张慧,薛东川. 三塘湖盆地芦草沟组页岩有机显微组分扫描电镜研究[J]. 电子显微学报,2019,38(3):257-263.
[20] LOUCKS R G, REED R M, RUPPEL S C, et al. Spectrum of pore types and networks in mudrocks and a descriptive classification for matrix-related mudrocks pores[J]. AAPG Bulletin, 2012, 96(6): 1071-1098.
[21] ROUQUEROL J, AVNIR D, FAIRBRIDGE C W, et al. Recommendations for the characterization of porous solid[J]. Pure and Applied Chemistry, 1994, 66(8): 1739-1758.
[22] 蔡振家,雷裕红,罗晓容,等. 鄂尔多斯盆地东南部延长组7段页岩有机孔发育特征及其影响因素[J]. 石油与天然气地质,2020,41(2):367-379.
[23] 程涌,刘聪,吴伟,等. 氩离子抛光—环境扫描电镜在页岩纳米孔隙研究中的应用以辽中凹陷JX地区沙一段为例[J]. 电子显微学报,2018,37(1):52-58.
[24] ZHU H J, JU Y W, HUANG C, et al. Tectonic and thermal controls on the nano-micro structural characteristic in a Cambrian Organic-Rich Shale[J]. Minerals, 2019, 9(6): 354.
[25] WANG G C. Deformation of organic matter and its effect on pores in mud rocks [J]. AAPG Bulletin, 2020, 104(1): 21-36.
[26] 蒋宜勤,柳益群,杨召,等.准噶尔盆地吉木萨尔凹陷凝灰岩型致密油特征与成因[J]. 石油勘探与开发,2015,42(6):741-749.
[27] 杨超,熊永强,张金川. 中国不同沉积类型页岩生烃有机孔发育差异[J]. 地球化学,2019,48(6):544-554.
[28] 李楚雄,肖七林,陈奇,等. 页岩纳米级孔隙在有机质熟化过程中的演化特征及影响因素[J]. 石油实验地质,2019,41(6):901-909.
[29] 吉鸿杰,邱振,陶辉飞,等.烃源岩特征与生烃动力学研究—以准噶尔盆地吉木萨尔凹陷芦草沟组为例[J]. 岩性油气藏,2016,28(4):34-42.
[30] 王朋飞,田黔宁,张玮,等. 氦离子显微镜在页岩有机质孔隙识别中的应用[J]. 电子显微学报,2020,39(3):274-281.
[31] 谢婷,张聪,杨玉茹,等. 贵州遵义黔XY1井龙马溪组页岩孔隙特征及主控因素[J]. 石油实验地质,2019,41(1):68-75.
[32] 葛明娜,庞飞,包书景. 贵州遵义五峰组—龙马溪组页岩微观孔隙特征及其对含气性控制—以安页1井为例[J]. 石油实验地质,2019,41(1):23-30.
[33] 高之业,范毓鹏,胡钦红,等. 川南地区龙马溪组页岩有机质孔隙差异化发育特征及其对储集空间的影响[J]. 石油科学通报,2020,01:1-16.
[34] 李二庭,向宝力,刘向军,等.准噶尔盆地吉木萨尔凹陷芦草沟组页岩油偏稠成因分析[J]. 天然气地球科学,2020,31(2):250-257.
[35] 曲长胜,邱隆伟,操应长,等.吉木萨尔凹陷二叠系芦草沟组烃源岩有机岩石学特征及其赋存状态[J].中国石油大学学报(自然科学版),2017,41(2):30-38.
[36] 潘树新,梁苏娟,史永苏,等. 松辽盆地上白垩统青山口组介形虫群集性死亡事件成因[J]. 古地理学报,2010,12(4):409-414.
[37] 张存霞. 基于岩石薄片分析的介形类化石赋存状态及地质意义—以济阳坳陷始新统泥页岩为例[J]. 地质论评,2015,61(6):1407-1416.