ND增强镁基复合材料的热膨胀性能研究
郑鸿珊1,张军伟2,马鸿斌1*,彭 勇2*
(1.青海大学 高性能轻金属合金与成形工程研究中心,青海省新型轻合金重点实验室,青海 西宁810016;2.兰州大学 物理科学与技术学院,甘肃 兰州73000)
摘 要 镁及镁合金由于其高比强度、比刚度、质量轻以及可回收利用等优点,而成为结构金属中广泛研究的重要材料。纯镁具有较高的导热系数,对镁及镁合金导热性能的研究有助于其在轻量化导热领域中的应用。本文通过粉末冶金的方法制备了不同添加量的纳米金刚石增强镁基复合材料,利用TEM、热膨胀仪等研究了其微观组织对热膨胀性能的影响。结果表明,纳米金刚石的加入可显著地细化镁基体合金晶粒,同时有效地降低其热膨胀系数,材料的尺寸稳定性得到改善。
关键词 镁基复合材料;纳米金刚石;热膨胀系数
中图分类号:TB331;TG115.21+5.3 文献标识码:A doi:10.3969/j.issn.1000-6281.2020.04.002
Study of the thermal expansion performance of ND enhanced magnesium matrix composites
ZHENG Hong-shan1,ZHANG Jun-wei2,MA Hong-bin1*,PENG Yong2*
(1.Qinghai Provincial Key Laboratory of New Light Alloys, Qinghai Provincial Engineering Research Center of High Performance Light Metal Alloys and Forming, Qinghai University, Xining Qinghai 810016;Key Laboratory of Magnetism and Magnetic Materials of Ministry of Education, Lanzhou University, Lanzhou Gansu 730000, China)
Abstract Magnesium and magnesium alloys havebeen extensively studied in structural metals due to their advantages of high strength, ratio stiffness, lightness, recoverable utilization and so on. At the same time, pure magnesium has a high thermal conductivity coefficient, and the research of the thermal performance of magnesium and magnesium alloys can be helpful to their applications in the field of thermal conduction. In this paper, the composites of nano-diamond reinforced magnesium matrix are prepared by powder metallurgy, and the effect of microstructure on thermal expansion performance is studied by using TEM and thermal expansion instrument. The results show that the addition of nano-diamond can significantly refine the grains of magnesium matrix alloys, effectively reduce the thermal expansion coefficient and improve the size stability of the material.
Keywords magnesium composite; nano-diamond; coefficient of thermal expansion
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[1] 徐志锋,陈超,吴开志,等. 颗粒尺寸对SiCp/Mg复合材料热膨胀性能的影响[J]. 特种铸造及有色合金,2012,32(10): 939-942.
[2] YAKUBTSOV I A,DIAK B J,SAGER C A,et al.Effects of heat treatment on microstructure and tensile deformation of Mg AZ80 alloy at room temperature [J].Materials Science & Engineering A,2008,496(12):247-255.
[3] 喻学斌,张国定,吴人洁. 电子封装铝基复合材料热循环曲线研究[J]. 航空材料学报,1995,15(1): 15-20.
[4] 罗晋如,GODFREY A,刘伟,等. 初始织构对高温轧制AZ31镁合金板的EBSD 研究[J]. 电子显微学报,2011,30(4):249-255.
[5] 刘俊友,施忠良,刘国权,等. 氧化的碳化硅颗粒增强铝-镁基复合材料的界面微结构特征[J]. 电子显微学报,2001,20(3): 206-212.
[6] 王金辉,栾世宇,张亚坤,等. 热处理对ZK60复合材料热膨胀行为的影响[J]. 热加工工艺,2018,47(16): 108-111.
[7] 王飞,孙威,刘林林. Mg-Gd-Y-Zn合金400℃热处理过程中长周期堆垛结构的形成[J]. 电子显微学报,2009,28(4): 361-366.
[8] 李万鹏,刘翠秀,陈斌,等. Mg-Y-Nd合金{10 1}孪晶界面稀土原子偏聚的电子显微研究[J]. 电子显微学报,2018,37(6): 563-470.
[9] DU X,DU D B,WANG Z H,et al.Ultra-high strengthening efficiency of grapheme nanoplatelets reinforced magnesium matrix composites[J]. Materials Science and Engineering A, 2018,711: 633-642.
[11] HASSAN S F, GUPTA M. Effect of particulate size of Al2O3 reinforcement on microstructure and mechanical behavior of solidification processed elemental Mg[J]. Journal of Alloys and Compounds, 2006, 419(1): 84-90.
[12] CAO G,CHOI H,OPORTUS J,et al. Study on tensile properties and microstructure of cast AZ91D/AlN nanocomposites [J]. Materials Science and Engineering:A,2008,494(1): 127-131.
[13] WANG X J, WANG N Z, WANG L Y, et al. Processing, microstructure and mechanical properties of micro-SiC particles reinforced magnesium matrix composites fabricated by stir casting assisted by ultrasonic treatment processing[J]. Materials & Design,2014,57(5): 638-645.
[14] SELVAM B, MARIMUTHU P, NARAYANASAMY R, et al. Dry sliding wear behaviour of zinc oxide reinforced magnesium matrix nano-composites[J]. Materials & Design, 2014,58(14): 475-481.
[15] ZHANG H, ZHAO Y, YAN Y, et al. Microstructure evolution and mechanical properties of Mg matrix composites reinforced with Al and nano SiC particles using spark plasma sintering followed by hot extrusion[J]. Journal of Alloys& Compounds, 2017,725: 652
[16] 刘少平,揭小平,闫洪,等.SiCp尺寸对AZ61镁基复合材料组织和性能的影响[J].热加工工艺,2009,38(18):61-63.
[17] SHAO B, WU S, SHAN D, et al. The effect of thermal cycling process between high and low temperatures on the microstructure and properties of Mg-10Li-3Al-3Zn-0.25Si alloy[J]. Materials Letters,2019,254:167-170.
[18] 杜磊,闫洪凌,李石保. SiCp/AZ61镁基复合材料的热膨胀性能研究[J]. 特种铸造及有色合金,2011,31(1): 70-72.
[19] 李元元,程晓敏,何高,等. Al-Cu-Mg-Zn合金相变储热材料热循环稳定性研究[J]. 热加工工艺,2012,41(22):107-109.